OKay... let's set aside affordability and quality of hardware that separates film and digital to produce prints either as a hobbyist, professional, or commercial enterprise and address the impact that PWP as software offers regarding digital image data access and manipulation.In other words, how do I take a digital file and use PWP so that it fools the film enthusiasts into thinking it was shot on film?
As background take a look at this "DPR Feature: Apical dynamic range interview" [ http://www.dpreview.com/news/0903/09031801apical.asp ] to see possible trends towards processing digital dynamic range in-camera.
I believe that in order to achieve a 'film look', a digital camera image file with near full dynamic range, good exposure, and good focus after a basic RAW conversion needs to be (1) separated into visual elements; (2) each visual element optimized for brightness, contrast, and color; and (3) the visual elements re-combined into a single 0 to 255 gray tone image file of infinite colors without objectionable halos (auras), artifacts, or tone reversals.
PWP5's 3-Zone Adjustment transform using (1) symmetrical tone range masks; (2) tone range specific contrast, brightness, and saturation adjustments; and (3) image version blending in the HSV color space model offers easy user access to an image's data and its manipulation to achieve a 'film look'. See: Multi-Zone Adjustment: http://www.dl-c.com/Temp/pwp50beta/down ... stment.pdf.
For serious digital image data access and manipulation, I tend to use manual techniques with: (1) Mask Tool symmetrical and asymmetrical tone range/image area masks; (2) Brightness/Color Curves for brightness, contrast, and color edits; (3) highlight tone range edits in the HSL color space model, mid-tone tone range edits in the RGB color space model, and shadow tone range edits in the HSV color space model; (4) image version blending with Stack Images/Composite-Blend; and (5) optimized specific image area 'One to One' cloning... followed by crop for (6) composition; (7) 'Creative' sharpening; and (8) 'Output' sharpening.
As digital images are not created 'equal' there may not be a 'magic bullet' or a generic workflow applicable to all images... I tend to enjoy taking my time with an image to maximize its potential... which at times results in 'over-processing'. You are welcome to visit: http://www.ncplus.net/~birchbay/09/IMAGEsbyDEN_09.htm to see my latest recorded near world view or experiment... ask if there are questions.